Ferric ion catalyzed decomposition of hydrogen peroxide in acetonitrile-water mediums.
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چکیده
منابع مشابه
Kinetics of the decomposition of hydrogen peroxide catalyzed by ferric ethylenediaminetetraacetate complex.
Added substrates, acetone and t-butyl alcohol, strongly retard the decomposition of H(2)O(2) brought about by ferric ethylenediaminetetraacetate (EDTA) at pH 8-9.5. Their relative effectiveness and the kinetic form of the retardation are consistent with their interruption of a hydroxyl radical chain that is propagated by HO. attack both upon H(2)O(2) and on complexed and uncomplexed EDTA. Simil...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1979
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.27.789